I know like 3 websites but you have to watch them on your computer (can't burn them onto a CD or anything; thats the only way to get movies free
has alot of shows (I watched all of Band Of Brothers on here)
has TONS of shows (cartoons and real like 24) and a fair selections of movies (I watch Venture Bros. here lol)
peekvids.com has even MORE selection, though some of the shows and movies don't work (It might just be my crappy computer
Hope these are good enough!